My take on this (other than the good advice regarding the toxicity) is that you wish to reduce the seepage. I would surmise that since flyash (not bottom ash or near spigot flyash) is many silt sized, it may be less permeable than the stratum beneath. Also, fly ash, being "granular" in cohesion (not cohesive) will settle nicely. Given this, you will want to estimate the permeability of the fly ash in a "settled state" - presuming you are dumping through water. Once you know this, you can determine the thickness of the needed flyash to yield your required maximum seepage rate through the flyash into the underlying stratum. Sure, bentonite would work well and many use it. I remember reading some papers on how to "spread it". The ice idea is a good one (given you have ice - but if in Thailand or Indonesia, well . . .) - used this on a stabilizing berm for a causeway across very soft varved clays in northern Quebec once. Placed the berm on the ice, the ice melted and the berm "fell into place" so to speak. Hope you find something that will tweak you. Best regards.