metgist;
I checked my C&S connect and indeed found this code case. Thanks for this information. I reviewed all submitted background information associated with this code case including background code committee correspondence. There was some apprehension regarding use of this material, identified as;
Mannesmann WB36 (DIN 15NiCuMoCb5) VdTUV 377/2 Microalloyed Carbon Steel.
The reason for the code case was to permit use of this microalloyed material based on limited service experience in Germany. This code case has not incorporated into Section I.
I will caution you that code cases are not necessarily approved for use by various Jurisdictions or regulatory bodies. Second, clients may not permit code case materials for boiler construction. As far as your original question, there has been nothing brought forward at code committee meetings regarding concerns for copper precipitation, and adverse effects on long term properties.
I would verify service experience with the original material supplier (Mannesmann) because they were the ones bringing forward the code case submittal over 10 years ago.