Usually floating ball valves are in the lower-pressure classes with resilient seats but with extrusion-resistant polymers the valves are offered up to around 6000 psi. As long as the valve relies on polymeric seats, the temp limit of the valve will be defined by the polymer. Embellishing a bit on what zdas04 stated above: floating ball seats are usually flexible and preloaded (crushed) against the surface of the ball. This way they shut off at low pressure differentials and although the ball is designed to be able to move into the downstream seat, the actual travel is pretty small. Most of the time, both seats seal. This can trap high pressure liquid inside the ball and cavity, and for cryo liquids, Chlorine, etc. it is necessary to drill a hole in the upstream side of the ball to release the pressure generated if the liquids vaporize. A good supplier will have developed mind-boggling arrays of seat technologies for various materials, pressures, temperatures, and other applications criteria.
Valves without elastomers can work at elevated temperatures; Valvtechnologies and Mogas use hard alloy balls and a hardfaced seating surface in the body, and the ball is lapped to the seat. Generally the ball is loaded against the seat by a spring mechanism/belleville washer and these valves are unidirectional, but just the ticket if you want to isolate superheated steam.
A 6" Ball weighs around 200 pounds. That's a lot to support on two polymer seats. Trunnion valves have an advantage for higher pressure valves as well as larger size valves. The seats, as mentioned earlier, are spring loaded against the ball(springs, belleville washers, even o-rings are used) AND the upstream area of the seat is larger than the downstream area of the seat so that increasing process pressure loads the seat against the ball. The loading mechanism pretty much dertermines how much crud the valve can tolerate: O-rings are used for paper stock, but coil springs can be used on clean steam. Trunnion valves can have seats with polymeric inserts, or the seats can be metallic for extended pressure/temp range.
Refer to my granite slab which bears the engraved message: There is a best valve for every application.