additions such as thorium (up to 2wt%) and Zirconium change the thermionic emisivity of the electrode - which is essentially the amount of charge required to strip an electrode from the electrode surface. the addition of thorium allows for easier electrode stripping and thus reduces electrode heating. textbooks suggest that the 2%th electrode is great for straight current applications (dcen), where the anode end (the electrode) heats up more than the cathode end (the workpiece). they suggest that you use a 2%th electrode for steel, cause straight polarity welding concentrates the majority of arc heat at the electrode tip. (actually, 70% of electrode arc heat is located at the anode end, whether welding in straight or reverse polarity). I do a lot of aluminum 6xxx welding and use a 2%th electrode, not pure. aluminum welding, which operates in ac, does not heat the pointed electrode enough to create a ball tip, so a pointed tip remains thoughout the welding process. as a result, the weld arc is much more directional and allows for better root penetration. hope this helps.