Mandy:
Hard Chrome is usually applied over a nickle flash. It goes down highly stressed and cracks upon application, however but the hairline cracking does not affect it's preformance.
Because Hard Chrome entails the use of several environmentally unfriendly compounds we are supposed to be getting rid of it.
WC is applied in two parts. A bondcoat of something like NiCrAlly is applied before the WC can adhere.
The surface finish before the thermal spray needs to be rougher than a 50 RMS because the bond with the substrate is primarily mechanical engagement of the coating with the asperities of the prepared surface.
The HVOF process involves burning a fuel with O2 and using a DeLaval nozzle design to force the exhaust gas produced through a constriction and then let it expand to supersonic speed. The coating is introduced as powder into the gas stream and propelled against the substrate. Nozzle to work distances are in the neighborhood of 3 to 6 inches. Cooling jets impinge on the part during during application to prevent overheating of the part.
Extensive masking is required to keep the thermal spray from unwanted areas. This can be in the form of non-contact "shadow masking" or thermal tape. Shadow masking is more expensive, but the edge of the coating often chips off when the tape is removed.
The resulting coating has a bond strength of around 10,000-15,000 lbs max. it is essentially a ceramic and is suitable only for areas which will not see any flexure, since it has no ductility. From my experience it does not do very well when subjected to scraping or pressure loading such as that of ball bearings. If your part is big , and there is line of sight axcess to the area needing wear resistance and the contact is sliding, then WC might be a good choice
UncleSyd is right about the local nitride, also there is another process called ElectroSpark Deposition which Pacific Northwest National Labs has been using to apply wear resistant coatings to nuclear reactor components for a number of years. The no masking is needed and the coating is absolutely superior, but the process snail slow, though automatable.