You really should provide more details on the pump and system so we can provide meaningful comments. It is possible for a pump to cavitate even if it has a very high NPSH margin. The most obvious causes are pre-rotation or sump configuration for vertical turbine pumps, operation at excessively high or excessively low flow, poor suction line configuration for a double suction impeller, vortexing, dissolved gases, hidden suction line restrictions (start-up strainer, dropped valve gate), etc. And since NPSH(required) is usually defined as cavitation sufficient to produce a 1% or 3% head loss, the pump manufacturer never tells you what suction head is required to suppress all cavitation (insipient cavitation). I have pumps that cavitate constantly and destroy the impeller every 6 months even running with ideal suction piping and a 100 foot NPSH margin. On paper, these pumps should not cavitate at all. But they do. After battling for many years, we finally found a design mistake regarding the diffuser throat geometry. .
Johnny Pellin