Well you need to obtain the Cv versus opening data for the valves in question.
You would normally try to operate within the 30-70% open position of a control valve so that will give you your mac and minimum valve CV.
Then there are many on line calculators to calculate flow for a CV given the different gas inlet conditions. e.g.
and scroll down for air and other gases
Then you can find max / min gas flow for your pressure drop.
I would then check with the valve vendor once you've found this or simply ask them to do the calculation.
40 bar to 32 bar pressure drop seems a bit strange to do and if these valves are manual any change in pressure up stream won't be accounted for.
It's also a little strange, if not potentially dangerous to ask someone who's never done this to do a design. I sincerely hope you have someone to check and authorise this work. If not don't do it.
The Grove valve you note appears to be a standard ball valve. They do not work well in pressure regulation service. Don't use one for this purpose unless it is designed for it ( I might be mistaken).
Remember - More details = better answers
Also: If you get a response it's polite to respond to it.