Torquey,
The primary path for heat transfer in an exhaust valve is through its contact with the valve seat. And since your exhaust valve is an axisymmetric part with a relatively uniform input of heat flux, it should not experience much distortion with temperature. The heat input into the valve varies during an engine cycle, due to things like exhaust gas pressure and temperature, intake/exhaust flow overlap, A/F ratios, and engine load.
The leakage rate of your seated exhaust valve will be more affected by the heat transfer rate between the seat and head than anything else. With a small valve head diameter, overheating should not be a problem. Your exhaust valves should not see temps higher than about 1300degF, even with high levels of supercharge. But if you want to check exhaust valve leakage at operating temps, you will need to make sure that the valve, seat, head, etc. are all at the correct temperature, not just the exhaust valve.
Additionally, pressure leakage past the piston rings is likely much more detrimental than any leakage past the exhaust valve seats. So maybe you're efforts might be misplaced.
Regards,
Terry