Refer to thread 391-21572.
A condenser is a heat exchanger. Develop, for your better understanding of condensers, a generic understanding of heat exchangers: area, LMDT, fouling factor,...
The functional relationship between cooling water temp. and exhaust pressure (all other things being constant) is monotonic, and does not have a "critical point".
As you move further from the condenser's design point, the exhaust pressure will increase faster, but it will be a smooth curve.
If you are observing a "sudden change in exhaust pressure", this is because something else is changing at the same time (perhaps the amount of dissolved gases (air) in your cooling water).
If you are HOPING to attain such a critical point of "sudden decrease of exhaust pressure" with your system, stop hoping.