Nielse:
Water or any other liquid has very many different boiling points at different pressures. For example, water boils at 100 deg C at a pressure of atmospheric pressure (101.3 kPa), or at 82 deg C at half of that pressure, or at 121 deg C at twice atmospheric pressure. In essence, a liquid has an infinite number of boiling point temperatures because it may exist at an infinite number of different pressures.
When we plot a graph of boiling point temperature versus pressure for any liquid, we obtain what is called the "vapor pressure graph" for that liquid.
Now, to answer your question. At atmospheric pressure, as we begin heating water, the "vapor pressure" of the water increases. That means that the amount of "water vapor" present in the air just above the surface of the water increases. In general usage, we don't refer to that "water vapor" as steam.
When the water temperature reaches the atmospheric pressure boiling point temperature of water (100 deg C), then and only then does "boiling" actually begin. Once boiling has begun, in general usage, we then refer to the evolved vapors as "steam".
In other words, "steam" is the vapor that evolves after the water boiling point temperature at the system pressure is reached and actual "boiling" begins. You asked for how much "steam is produced at temperatures approaching the boiling point" and the precise answer to that question is "none" ... because steam is not produced until the water is at its boiling point temperature (under the system pressure) and boiling actually begins. Before the that point, the amount of water vapor above the water surface increases ... but we don't call that steam. In other words, as the water temperature approaches the boiling point, the humidity of the air above the liquid is increased ... but that is not called "steam".
Milton Beychok
(Visit me at www.air-dispersion.com)
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