Patrick,
I can only GUESS that your Grade B is defining the material to be equivalent to A106 Grade B which has a lower yeild than the minimum grade shown in MSS-SP-75 and they want the fitting to otherwise be in accordance with MSS-SP-75.
You need to go to your source and get this verified and specify it so there is no confusion.
Also, what grade of pipe is used with these fittings? They should be the same or similar grade. If they differ, verify that the lesser grade has an adequate wall thickness to handle the design conditions.
Good luck,
NozzleTwister
Houston, Texas