Although this is an old posting of sorts, I thought I'd add my 2¢ worth:
typically, most fluorescent lighting I've been accustomed to uses the "cool white" bulbs -- which drive my eyes nuts and have routinely given me headaches (I even tried the eyeglass tinting recommended for fluorescents -- to no avail)
I tried the "daylight" bulbs which give off a bluer light and are not as glaring or harsh and provided the relief I needed -- as a result, I have also implemented installing these lamps in the control rooms at our power plants...
initially some employees have made fun of the "blue" light (it's only significantly noticable when the "cool white" lights are near), but almost all seem to prefer these type bulbs after working under them -- they have been a little pricier than "cool white" but can be a direct replacement rather than fixture changeouts, etc...