Just to confirm that Gerhardl, as usual, is absolutely correct.
Solid ball means the part is made from a solid sphere and a hole is drilled through to make a the flow path. So between the flow port and the outer surface of the sphere, the ball is solid.
Hollow ball is when the inside of the sphere is "hollow" There is a certain thickness to the shell to give it strength, but unless you weld in a piece of pipe, the flow port through the ball will not be circular.
Hollow balls are used to save weight and cost, and are only useful in large valves where the weight of he ball becoms significant. The concern with hollow balls is the strength under pressure when valve is shut, and more importantly, the strength of the ball / stem connection for opening and closing the valve.
Both solid and hollow balls can be made from one material, or a material that is coated with hard facigns such as tungsten carbides.