There's no overpressure allowance for tanks similar to ASME section 8.
If the tank is designed for 2" of WC, you can take credit for the emergency vent IF it achieves the required flow rate without exceeding 2" of WC in the tank. What type of emergency vent is it? If it's a pop-off device that sits on a manway you may be fine, if it's similar to the Groth vent valves (which require pressures higher than set to achieve a flow through them) you won't be.