The hydrogen molecule, because of it's extremely small size, will diffuse through the solid steel wall. In fact, there are formulae and curves to describe this phenomenon. However, it depends on the hydrogen partial pressure. if you have a repad on the outside of a vessel, hydrogen will diffuse into the space between the pad and the vessel shell. Normally, the weep-hole that was drilled into the repad should be sufficient to allow the hydrogen to escape. However, these weep holes often get forgotten or filled, and hydrogen pressure can build up. Not a big deal, until the vessel de-pressurizes, and the hydrogen tries to escape, and ends up pressurizing the vessel shell under the repad. After a few cycles of that, your fillet welds will likely crack, and your re-pad will no longer be "attached" to the shell. It's a similar process as you would see in hydrogen blistering...