For transferring heat, no fluid even comes close to being as good as water. It has an amazing heat capacity. From the perspective of maximizing heat transfer, the ideal concentration of glycol is zero. The only reason glycol is added to coolant systems is because water has the unfortunate property of freezing at 0 degC. Glycol lowers the freezing point of the coolant system so that it can be operated at lower temperatures, without freezing. So, if you need to operate at a lower temperature, then proceed with considering a higher glycol concentration. But, the trade-off will be poorer heat transfer. That's the price you pay for operating at a lower T. To compensate for that, run the coolant at a higher flowrate, or modify the exchanger to acheive a higher heat transfer coefficient. If your system is operating well, and you want to improve the heat transfer, then consider changes to the heat exchangers (to get a higher U value), or consider reducing the glycol concentration if that can be done without getting too close to the freezing point.