The A number only applies to ferrous metals. Assuming the contractor is welding a nonferrous alloy, the A-number is not an essential variable to consider.
Just because the code may allow a contractor to do something is not justification to do something that is not reasonable from an engineering standpoint. There are many things to consider in addition to the essential variables listed by ASME Section IX. For instance; Joint detail is not a consideration, i.e., it is not an essential variable for the GTAW process. If the contractor qualifies the WPS using 1 3/4 inch thick material, the range of thickness qualified extends to 8 inches. While Section IX does not consider joint details as an essential variable, I believe most people recognize that switching from a V-groove with a 60 degree groove angle to a square groove with no root opening and using GTAW with a 3/32 inch diameter tungsten has little probability of success if the base metal thickness is 5 inches thick.
ASME has no provisions for common sense. The following essential variable does not appear in Section Nine: Does This Make Sense? The person making decisions must be competent and understand weld technology.
Best regards - Al