You really need to have a welding engineer / inspector assist you as it dpeends which welding code you use. Some have fairly wide ranges of materials , sizes and wall thickness which a particualr Weld Procedure Specification (WPS) is applicalble for, others less so. My limited knowledge of Duplex welding is that it requires an inert gas (argon) type of welding and requires high quality welders, but whether you could use a piece of C Stl in place of duplex but a WPS which is OK for duplex I don't know. Ask a specialist, but you do need to tell him which code you are working to.
In general your WPS then needs to be tested by undergoing various NDT and destructive tests to "prove" the WPS ina test, the WPQT. These tests are then approved by the relevant welding inspector from the client or your own internal inspector, again to what ever criteria it says on your welding code (B31.3, ASME IX etc). There is sometimes a time limt on the approval of the WPS Whichever welder did the weld is then automatically approved for that procedure.
Other welders then need to do a more simple test to that procedure, using either a test piece or their first production weld. That weld in then inspected by NDT by the approved welding inspector and if he passes, then he is also approved and on it goes.
This is what B31.3 says is required in general as part 328.1 and I would imagine other design codes say simialr things
" Each employer is responsible for the welding done
by the personnel of his/her organization and, except as provided in paras. 328.2.2 and 328.2.3, shall conduct the
tests required to qualify welding procedures, and to qualify and as necessary requalify welders and welding
operators.
My motto: Learn something new every day
Also: There's usually a good reason why everyone does it that way