From your description, the pumps are definitely pumping in parallel on the discharge side, but I can't decipher what you mean about the suction side. If the pumps are pumping from the same suction side system (e.g. the same pipe manifold, the same tank, even the same network, etc.), then the pumps are fully parallel. However, if the suction sides are different (e.g. pumping from separate systems), then the pumps are not fully parallel. Regardless, the fact that at least the discharge side is parallel here means that each pump will see the effect of the other pump running or not running and this can affect your combined capacity.
Depending on how important the answer is, you may want to model the system, including pump curves, tank levels, suction and discharge piping (including any networks on the suction side), diurnal demand fluctuations, etc. This way, you can try different operational scenarios and see what is really happening. You also need to define what the real goal is. For example, is the goal to pump 10,000 gpm or is the goal to move (say) 10 million gallons per day? If the goal is 10 MGD, then the average is only 6,944 gpm and your pumps should easily manage that with a combination of single and dual pump operation, even if the combined output is less than 10,000 gpm.
Unless the discharge side is hydraulically insignificant, when both pumps are running simultaneously, the total flow will be measurably to significantly less than the sum of their individual outputs. An example of "hydraulically insignificant" would be something like a short, large-diameter discharge pipe that exits above the maximum water level in the open tank. If the discharge pipe exits "under water," then the varying level in the open tank must be taken into account. As the hydraulic conditions in the suction and discharge sides vary, pump capacity will vary. Thus, a nominally 5,000-gpm pump may actually pump from (say) 4,000 gpm to 5,800 gpm depending on conditions.
Please note that pumps with relatively steep pump curves (like many VT pumps), will show less reduction in capacity than would pumps with relatively flat curves. In addition, pumps with different curves will not always play nice together.
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