I'd double check the PSV calc before I put much work into figuring out if the lid will blow off the tank. It looks to me like you are between an "E" and "F" orifice if you've talking about 10 MMSCF/day. An "E" works out to 8.9 MMSCF/d and an "F" to 12.7 MMSCF/d for a 0.7 SG gas at 80[°]F.
Then you need to decide how much pressure you feel safe putting on the tank (it should be a pretty small number).
Then you need to look at the length of the 8" vents. If it they are longer than about 3D, then you need to do a pipe flow calc using the dP you decided was safe above. If the vents are shorter than 3D then you need to do a nozzle calc with the dP to get the flow rate up the vents.
If the two vents can move significantly more than what you calculate then you are fine (i.e., the maximum pressure won't approach the safe value). When I get pushed into a corner and have to do this kind of calculation I typically use a safety factor of 2 (i.e., can each pipe move the entire volume by itself at the maximum dP?).
David Simpson, PE
MuleShoe Engineering
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