It's hard to say without understanding how your system works and therefore what happens in a blocked outlet case.
In most fuel drums I've seen a variety of streams flow to it from various sources under usually pressure or flow control. From the fuel drum, the mixed gases flow to the various users. Natural gas is usually the final variable to control fuel gas pressure with a vent valve to flare if the pressure gets too high.
Given this, the temperature doesn't usually vary much if I was to envision a blocked outlet. The incoming streams would (typically) be assumed to continue at the same flow rate even if the controllers would take some action because typically, you do not take credit for instrumentation (however, if an instrumentation should take action that would make the relief case worse, I assume it does respond and include that in the required relief flow).
Now, how this compares to your system and what is the overall control system is something you need to consider. Temperature isn't a huge factor in sizing a relief valve.
I'd size the relief valve and then based on the difference in areas between the required area you calculate and the next available PSV orifice size, I'd see just how critical the temperature and other assumed properties are (MW for example, flow, etc) for being satisfied you have sufficient relief capacity.