Check out suggested span to depth ratios for a start. Bands are around span/25 and slabs are span/40.
Find the minimum duct cover, generally about 1" cover for 2hr fire rating and 1.5" cover for 4hr. Best to put in tendons to reverse the bending moment diagram and try to have 1.4 to 2.0MPa prestress. Keep tendons about 800-1200 centres but can be closer spacing in bands or column strips.
I always place reinforcement over the columns to help with punching shear and peak moments, generally 16mm bars at 200mm centres.
Keep tendon lengths to about 30m otherwise losses are large and tendon loses it's effectiveness, also 30m x 30m is a good size for a concrete pour (200-250 cubic metres).
I generally like to size the slab thickness with 1.4-2.0MPa prestress for deflections and shears first. When designing for flexure the tendons will normally have capacity to do it by themselves except over columns or other supports.
To study up on it find a good PT publication, I think there is one by concrete society which is good and also read through some of rapt's post that he has put on this website because they know PT design better than most.