A material above its autoignition temperature is likely, when leaked, to mix into air at a concentration exceeding both its AIT and the lower explosive limit, hence resulting in a fire. But if the material leaks and cools below its AIT, that's even worse because the PIPE is operating above the AIT and hence behaves as if it were a spark or open flame- the PIPE itself will ignite the vapour. If you think the insulation around the pipe is vapour tight and will suppress a fire, think again...
Area classification significantly reduces the risk that electrical devices will be the source of a fire. However, in hazardous areas that already contain a non-electrical source of ignition such as hot pipe, a burner, the exhaust of an engine... area classification does nothing but give you a false sense of security. Instead, you need another means to mitigate the risk of fire and explosion: ventilation, layout, reduction in leakage points, gas detection, fire detection and suppression etc.