Lionel - It is possible to use the 2 kVA transformers as autotransformers in an open delta connection to provide 240V, 3-phase power. Each 2 kVA transformer's 32V boost winding "stretches" one side of the 208V phase-phase voltage triangle out to 240V. The result is three phase-phase output voltages at 240V but the phase to "neutral" voltages would be 223V, 120V and 223V. The panel could only feed 240V loads. It would be dangerous to have it feed a 120V load.
The system is still grounded via the grounded neutral of the 120/208V system. The autotransformer does not isolate the system. A new grounded, "neutral" cannot be established unless a two winding transformer is used.
The 2 KVA autotransformers' 32 V windings are rated for 2kVA/32V = 62.5A. 62.5A x 240V = 15KVA per autotransformer. The two 2 kVA transformers could feed (2 x 15 kVA) = 30 kVA of load. (This isn't quite correct. The 3-phase KVA rating for the open delta bank is different because the two transformers also supply power to the third phase. Search for other threads on open-delta connections, there have been some excellent posts on this subject.)
This arrangement matches the rating of the circuit breakers mentioned by the OP.
Could be confusing to someone just looking at it. While this is a good cost effective design, it could be made better by a couple of nameplates, "CAUTION - 240V PANEL. DO NOT CONNECT 120V LOADS." or "Supplied from 208-240V Autotransformers - Do not connect 120V loads."