That won't work. Besides, the acidic soil will attack the concrete first.
Consider using higher density concrete (adding silica fume for instance) and increasing the cover on the rebar. Find out the level of acidity. You might be able to use stainless steel rebar or epoxy coated rebar to help, but painting the rebar with an epoxy primer would result in concentrated areas of corrosion due to "holidays" in the coating, porosity in the coating or lack of bond between the coating and the steel.
Further, painting will compromise the bond between the steel and the concrete. Epoxy coated rebar doesn't have that issue.