a 5.45 order is generated by a puls with a frequency of 5.45 the running speed. The term "order" refers, to the referring speed (usually the running or driving speed of an installation or plant). Usually, this are even numbers, unless through a combination of gears you have shafts with differents speeds.
An example: a six cilinder 4-stroke engine (one combustion cylce per two revolutions) generates a 3rd order (and harmonics).