A194-4 nuts include Molybdenum and have a higher minimum tempering temperature.
While B31.3 rates both nut materials for use up to 593 deg. C., I'm used to seeing the bolting for A335-P11 piping to be A193-B16 studs with A194-4 nuts for operating temperatures above 400 deg. C.
NozzleTwister
Houston, Texas