Pleckner,
Your comments are appreciated and your words of caution are duly noted. I do agree that flow through a nozzle is isentropic (that is well established thermodynamic theory) and I continue this discussion only to further my understanding of what I've seen in the literature.
Since my last post, I've discovered 2 more articles that indicate or imply that isenthalpic flash from relieving pressure to downstream backpressure would be sufficient. However, there may be a pattern to these claims and it seems to be associated with two-phase flow conditions.
Just conjecture on my part but maybe it is the presence of liquid that would allow such approach without much error. Looking at a pressure-enthalpy diagram, for systems that remain liquid or are low in vapor fraction, the change in entropy with change in pressure doesn't appear to be as great compared to systems that remain vapor or are high in vapor fraction. Also, maybe since a nozzle seems to be less "efficient" for liquid flow than for vapor flow (as evidenced by typical valve discharge coefficients) has some bearing on how closely the process follows the theory.
Anyway, additional comments by all are welcomed. Below are the additional references and I've included a full excerpt from Perry's.
From Perry's 7th edition, Section 26 - Process Safety, Vent System Flow Capacity,
"The presence of both liquid and vapor phases in the vent stream is normally treated as a vapor-liquid mixture at equilibrium conditions. The adiabatic flashing of the stream as the pressure falls along the flow path is usually computed by conventional flash distillation methods. In principle, the flash path should be isentropic for flow in devices exhibiting low friction losses (nozzles and short pipes). For friction flow, the sum of the stream enthalpy, kinetic energy, and potential energy is held constant along the path. In practice, little error is introduced by carrying out the flash computations at constant enthalpy. With this simplification, the flash temperature-pressure-composition history can be established before starting the actual flow calculations, thus eliminating the need for repetitive flash calculations at each step in the integration."
Leung, J.C., "Easily Size Relief Devices and Piping for Two-Phase Flow", Chem.Eng.Progress, p.33, Dec-1996. From the section discussing Nozzle Flow -
"For two-phase flashing flow, the P-v relation should be given by a constant entropy flash calculation. However, in practice, the result is almost indistinguishable when a constant enthalpy (isenthalpic) flash calculation is used; the latter seems to be much more common with commercially available flash routines."
Later in the same article there is some discussion about the accuracy of the above assumption.
"This deviation is due to the difference between the assumed isenthalpic and the actual isentropic expansion processes."
Fauske, H.K., "A Practical Approach to Capacity Certification", Chemical Processing, Feb-2003. This article can be accessed from the internet
In the section of the article discussing sizing of the outlet piping the following example is given for a 1 percent steam-water mixture with a set pressure of 35 psig.
"The maximum allowable backpressure, P1 = 35 x 0.1 + 14.7 = 18.2 psia. Considering an isenthalpic flash to this pressure from 53.2 psia results in x1 = 0.075."
From API RP-520 Part I, 7th edition, Jan-2000, when following the "Omega" method for sizing for two-phase flow, the following is noted:
"v9 = specific volume evaluated at 90% of the PRV inlet pressure Po (ft3/lb). When determining v9, the flash calculation should be carried out isentropically, but an isenthalpic (adiabatic) flash is sufficient."