rahulsb,
Do you have good level control on the tank? Could you tell when a certain level was reached by the recorded historic of the levels?
If yes, you could open a dedicated entry just for the relief valve. If you size it accordingly and never let the liquid level reach it by proper level control, even sticky material wont be a problem. (add it to a preventive maintenance plan or routine checklist anyway). If a critical level is reached, it would warn you about the need of cleaning the valve.
OBS.: I'm assuming that you have a product with a very low vapor pressure and small liquid movement inside the vessel. But I've already seem cases where components with a relatively high boiling point got carried to the relief valve and plugged it. That's why a routine verification is never a bad advice.
In God we trust. All the others must bring data.