virgil98765
Chemical
- May 6, 2009
- 3
someone wrote in earlier, closed thread:
In most areas, some type of vapor control system will be required for gasoline and ethanol storage tanks. (I am assuming the location of the tanks are in the US.) As IFR states, you can install Internal Floating Roofs on the tanks to control the vapor emissions(IFRs). However, blanketing will not control the emissions unless the blanket pressure is sufficiently higher than the TVP of the product in the tank. Unfortunately, most gasoline and ethanol storage tank's design pressure is not high enough to blanket at a high enough pressure to reduce the emissions adequately.
Therefore, blanketing is usually not an option. You will likely be required to put some time of vapor control system on the tanks like an IFR. Another alternative is to install a common header that connects all of the vapor spaces of your fixed roof tanks. At the end of this header, a carbon adsorption based VRU can be used or a combustion system that safely burns the generated hydrocarbon vapors. Explosive mixtures can be controlled without blanketing. There are several manufacturers of this type of equipment.
jwy
>>I can't disagree with this more. The food, distillery, biotech, semiconductor and other industries have been using nitrogen blanketed alcohol storage tanks for years. Now the petrochemical industry is trying to convert over for the new alcholol blends using floating roof tanks.
Here are my replies to the above:
However, blanketing will not control the emissions unless the blanket pressure is sufficiently higher than the TVP of the product in the tank.
>>>yes, this is true, and it is a positive because you will need to provide a nitrogen blanket higher than the TVP. That is one of the "prime" purposes of providing a nitrogen blanket- emission control providing a sealed tank design as well as elimination of oxygen in potentially explosive air space inside these tanks.
Unfortunately, most gasoline and ethanol storage tank's design pressure is not high enough to blanket at a high enough pressure to reduce the emissions adequately.
>>>Well, then there you go, that says that these tanks are not suited to storing the material in the first place! Process chemical engineering 101 comes into play here as well as some common sense: design the tank with the proper design pressure and temperature not some trick verbage manipulations. Furthermore when you study CFR Title 40, part 60 subpart K, Ka and Kb in more detail, it says that these tanks, 40,000 gallons or more, shall not be for more than 11.1 psia. When you consider the vapor pressure of the fluid for hot summer days, which could easily exceed 150F internal tank temperature then you are well above this value.
Also, consider that these tanks are not designed per the material safety data sheet requirements (OSHA) which call for a completely tight container. These tanks provide for a vent above the floating roof in which an explosive atmosphere would exist with all three elements to foster a fire/explosion: fuel, oxygen, and ignition source.
At the end of this header, a carbon adsorption based VRU can be used or a combustion system that safely burns the generated hydrocarbon vapors.
>>>>Again, not recommended because all the Obama green hats won't have you increasing carbon foot print, it doesn't meet the OSHA MSDS requirements for completely closed tank and on very hot days you may lose your entire liquid phase out the incinerator stack. Carbon adsorption/carbon adsorption with product recovery provides a whole new set of safety and operating issues, I am not going to discuss these here except to say it's less expensive than going with nitrogen blanketing in the first place.
A properly designed tank with nitrogen blanket is the safest way to go in my opinion.
In most areas, some type of vapor control system will be required for gasoline and ethanol storage tanks. (I am assuming the location of the tanks are in the US.) As IFR states, you can install Internal Floating Roofs on the tanks to control the vapor emissions(IFRs). However, blanketing will not control the emissions unless the blanket pressure is sufficiently higher than the TVP of the product in the tank. Unfortunately, most gasoline and ethanol storage tank's design pressure is not high enough to blanket at a high enough pressure to reduce the emissions adequately.
Therefore, blanketing is usually not an option. You will likely be required to put some time of vapor control system on the tanks like an IFR. Another alternative is to install a common header that connects all of the vapor spaces of your fixed roof tanks. At the end of this header, a carbon adsorption based VRU can be used or a combustion system that safely burns the generated hydrocarbon vapors. Explosive mixtures can be controlled without blanketing. There are several manufacturers of this type of equipment.
jwy
>>I can't disagree with this more. The food, distillery, biotech, semiconductor and other industries have been using nitrogen blanketed alcohol storage tanks for years. Now the petrochemical industry is trying to convert over for the new alcholol blends using floating roof tanks.
Here are my replies to the above:
However, blanketing will not control the emissions unless the blanket pressure is sufficiently higher than the TVP of the product in the tank.
>>>yes, this is true, and it is a positive because you will need to provide a nitrogen blanket higher than the TVP. That is one of the "prime" purposes of providing a nitrogen blanket- emission control providing a sealed tank design as well as elimination of oxygen in potentially explosive air space inside these tanks.
Unfortunately, most gasoline and ethanol storage tank's design pressure is not high enough to blanket at a high enough pressure to reduce the emissions adequately.
>>>Well, then there you go, that says that these tanks are not suited to storing the material in the first place! Process chemical engineering 101 comes into play here as well as some common sense: design the tank with the proper design pressure and temperature not some trick verbage manipulations. Furthermore when you study CFR Title 40, part 60 subpart K, Ka and Kb in more detail, it says that these tanks, 40,000 gallons or more, shall not be for more than 11.1 psia. When you consider the vapor pressure of the fluid for hot summer days, which could easily exceed 150F internal tank temperature then you are well above this value.
Also, consider that these tanks are not designed per the material safety data sheet requirements (OSHA) which call for a completely tight container. These tanks provide for a vent above the floating roof in which an explosive atmosphere would exist with all three elements to foster a fire/explosion: fuel, oxygen, and ignition source.
At the end of this header, a carbon adsorption based VRU can be used or a combustion system that safely burns the generated hydrocarbon vapors.
>>>>Again, not recommended because all the Obama green hats won't have you increasing carbon foot print, it doesn't meet the OSHA MSDS requirements for completely closed tank and on very hot days you may lose your entire liquid phase out the incinerator stack. Carbon adsorption/carbon adsorption with product recovery provides a whole new set of safety and operating issues, I am not going to discuss these here except to say it's less expensive than going with nitrogen blanketing in the first place.
A properly designed tank with nitrogen blanket is the safest way to go in my opinion.
