Not enough information.
First, in most ofNorth America it is against the code to use a ground connection as a neutral.
Second, there are a number of different configurations that supply phase 240 Volts. The phase to ground voltage may be different.
1> Floating delta. (ungrounded).
In a large system where the charging current is balanced and is large in relation to your load, the phase voltage to ground will be about 138 Volts.
In the event of a ground fault on another phase this voltage will approach 240 Volts.
If the system impedance to ground is not balanced, the voltage from a phase to ground may be between zero Volts and 240 Volts.
2> Delta with a zig-zag or wye-delta grounding transformer.
The voltage to ground from any phase will be 138 Volts.
3> Corner grounded delta.
The phase voltages to ground will be zero volts, 240 Volts and 240 Volts.
4> Four wire, center tapped delta.
The voltages phase to ground will be 120 Volts, 120 Volts and 208 Volts (variously called the "Wild leg", or "High Leg".
The Four wire center tapped delta system is actually quite widely used in the US.
You may have this arrangement with the neutral landed on a neutral bus in the service panel. It is quite acceptable to use one phase to this neutral bus for 120 Volts.
If you don't have a four wire center tapped delta system with a neutral brought to the panel, then you are well advised to follow itsmoked's suggestion.
Don't use a ground for a neutral.
Bill
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"Why not the best?"
Jimmy Carter