Negative eigenvalue just means that the load to cause the buckle is of the opposite sign to the applied load. So if I applied a reference load of 1 MPa and the first eigenvalue was -0.5, then the load required to trigger the buckling mode is (1 x -0.5) = -0.5 MPa.
You may well get spurious buckling modes with eigenvalue extraction, I know I've seen them. After all, the eigenvalues are just the mathematical solution to the problem, they may not necessarily be physically possible. It's up to you, the analyst, to determine what is significant and what isn't.
Having said that, it's probably worth double-checking your constraints and loads anyway.
Regards
Martin Stokes CEng MIMechE