Above 110 A UL REQUIRES the termination be rated for 75 deg C wire. At 110 A and below, it's optional.
So if you KNOW what equipment you are getting and you specify 75 deg C termination, you can use that. But remember, this has to apply at BOTH ENDS of the circuit.
The most conservative approach is to size using 60 deg C ampacity up through 110 A and then use 75 deg C above that.