I wouldn't call 30% a small value. I think having the UY behavior split between modes two and 4 is an excellent reason why you would WANT to use the response spectrum method. Let's say you have moment frames at the top story and shear walls below that, this could easily result in the behavior you're seeing.
That being said, I would recommend reviewing those two modes (visually) and seeing if they make sense to you. And, that the split modes are not the result of some sort of modeling problem.