Gilles,
With respect, the answers you are giving tell me you really don't have a lot of experience in this field and you seem to be expecting miracles. What is your design code, what is the DESIGN PRESSURE of the pipeline, wall thickness, pipe grade etc (API 5L comes in many grades)
If your current two pumps are running at 90 bar inlet and your design pressure? is 100 bar, there is virtually no increase in flow available to you.
You need in practice to have a bit of a gap between max operating pressure and design pressure to allow for alarms, trips and relief valve settings. Typically this is 8-10% below design pressure.
So basically you are already operating flat out.
Pumps - I'm assuming these are centrifugal pumps - do not come in units of flow so 3 x "100m3/hr pump" does NOT mean you can flow at 300m3/hr. It depends on what the system curve of your pipeline looks like. Centrifugal pumps are essentially a constant pressure machine with variable flow.
What you propose - VFD - will not work in this instance as until the speed increases to the point where the head of the pump (proportional to speed^2) is equal to or a bit higher than the other two running pumps there will be no flow through this third pump.
All that will happen is that your three pumps will more or less share the flow between them, but this flow in total will not be more than 5% higher than what you are getting with two pumps. So there is no point in starting a third pump. However if you really really want to to prove the point then simply start it against a closed control valve (globe valve or similar) and then SLOWLY open it. Starting against a gate valve or a ball valve won't give you the control you need. Even then your three pumps might exceed you max operating pressure / pump high pressure trip.
Bottom line - give us ALL the information we've asked and then we can tell you for certain. But you can't re-invent the laws of fluid flow.
If you want more flow then you need to build a booster station at the hydraulic middle point. This might not be the middle of the pipeline physically. Depend son the topography / profile of the pipeline.
Remember - More details = better answers
Also: If you get a response it's polite to respond to it.