Well, dont believe the hype. This is a very sticky debate, especially about Solidworks and Inventor - everyone says something is best cos they use it. Scare stories about crashing computers works on both sides and should be taken with a pinch of salt, everyones had bad experiences at some point.
A good few points have been mentioned though. Get some decent demo versions, define EXACTLY what you want it to do and *dont* let the sellers show you a 'pre scripted' sales routine. Make them do something which is very hard to achieve in a 3d package related to your work and see how well the package (not necessarily the salesmen - unless they are your support team!) cope.
Im sure folk remember me on here, and no, we still havent decided which package to get!.
For example, we do Jigs and Fixtures and press tooling for automotive parts and exhaust systems. On a short trial of both Swx and Inventor it was found very difficult to model in "Car-Line" orientation (ie starting off on compound angle related to a bracket on a car exhaust at a point other than 0,0,0 in space and modelling other non contacting parts based from there etc),also manouvering the equivalent of the UCS about in relation to other parts was a real nightmare in both cases unless your initially very good.
MDT, which albeit is seen as getting old hat could still do most of our work, if not all of it. I like the feedom to do whatever the hell you want in it when you want, which is not the case in some other packages. Sheet metal and 'working' assemblies is admittedly poor though compaired to Inventor if thats your bag.
I like Inventor, from what Ive seen so far, its very slick and very impressive and not as far behind as other brands imply, infact it has some great innovative features. I dont care if this sounds funny too, but I felt more 'relaxed' with the interface compared to solidworks.....its very superficial I know, but its the truth.
If your main buisness is 'product design' and sheetmetal stuff then you should seriously look into the Inventor or Solidworks products, they are probably just as good as each other for general use - but its your speciality field you have to cover your arse on

so make sure you know EVERYTHING you expect it to do and that it does it simply enough.
They all work pretty much the same these days, and it will seem alien there being a different 'environment' and file types for say sheetmetal,drawing,sketching,assembly etc.
In autodesk stuff, for presstools I would lean at Inventor and for Jigs/Fixtures and detailing/non 3d work I would lean at MDT/series. For 2d mech work I would use Mechanical and for difficult surfaces Id spent 600 pounds on rhino3d. That is a hell of a lot of software to learn though!
We are in limbo what to do ourselves, its a difficult decision to make isnt it?, it will either work out great, or everyone will hate you for it and cost a lot of money....
A good understanding of thier shortfalls is essential, however this is not easy to come across without propoganda creeping in from different manufacturers. Its a minefield, and,like others,Im not wanting to get my leg blown off!.
If youre looking to stick with Autodesk, there is plenty of downloadable pdf's explaining the differences between the two. Somethings have to be seen to be understood or believed though, you dont appreciate what its saying until you need it!.
good luck.
See ya.
Sirius2