why not ask the plasma gun manufacturer for recommendations?
I am sure they will be more than helpful
each may have their own alloys/mixtures they spray
otherwise:
experiment using different qualities and the cheapest inserts should be given a chance as well, try anything
personally, I would sharpen inserts on a diamond grinding wheel by hand and get a sharp corner that can penetrate the material, the corners on the inserts are often rounded, and even sharp-corner inserts can be improved upon
I used to simply grind the top flat and get three times the tool life as well as excellent finish
Taking the inserts out of a box and using them ? Not me. Not for delicate work like that. Roughing may be ok if you have enough horsey power.