The issue it, at least here in the US (an I assume you are here because of the 480/4160 reference), the NEC requires that any transformer used to step up voltage, i.e. "reverse feed", must be specifically listed by the transformer mfr for that purpose. Without going into too many potentially irrelevant details, the usual issue is that, depending on how the windings are done, there can be extremely high inrush currents on the low voltage windings because they were not meant to be energized first, they were meant to have a voltage INDUCED onto them from the (originally primary) higher voltage. Transformer mfrs know all about this and will say, up front, if their design will have a problem or not. I was merely pointing out that you will need to ensure that whatever you use has been vetted for that purpose because it's now codified in the NEC.
And yes, you then need to determine the losses in the transformer because the soft starter will need to supply them. So because the transformer feeds the reactive power for the motor too, the kVA = motor kW/PF and most likely you will end up needing a 750kVA xfmr. Losses on a 750kVA dry type MV transformer could be as high as 15kW, or roughly another 30A at 480V, so you need to make sure your current rating on the soft starter is not "on the ragged edge" of the motor nameplate FLA.
"You measure the size of the accomplishment by the obstacles you had to overcome to reach your goals" -- Booker T. Washington