Clause 8.1.2 has three separate requirements for light metal content of enclosures:
• for Zone 0
10 % in total of aluminium, magnesium, titanium and zirconium, or
7,5 % in total of magnesium, titanium and zirconium;
• for Zone 1
7,5 % magnesium;
• for Zone 2
no requirements except for fans, fanhoods, and ventilating screens which shall comply with the requirements for Zone 1.
ATEX Zone 0 is an environment where an explosive atmosphere is frequently or continuously present, so I guess the even the minute risk of a thermite reaction between iron and aluminium is unacceptable. Zone 1 is an environment where an explosve atmosphere is likely to occur occasionally in normal operation, so the risk of an incendive spark and an combustible atmosphere being simultaneously present is consderably lower.
There is a further line in Clause 8.1.2 which allows use of light metals in Zone 0 subject to the user determining that there is very little risk of an incendive spark due to impact or friction, which gives some idea as to the origin of the requirement.