I am an Electrical Maintenance Department Supervisor at a US PWR and have been in this industry since 1974. First, realistically, I do not think any reasonable person would have a problem with ScottyUK's footer. Second, there is no real difference in the fundamental design of the electrical power systems except in terms of redundancy, separation, paper trail, and almost overwhelming administrative requirements.
The major issue for someone enetering this industry would be the acceptance of the culture. There are many redunant and intentional barriers in place to prevent inadvertent alteration of the design basis and to assure that the plant is always operating within the envelope of the design basis. These issues are significantly compounded by an extremely high level of concern (and related administrative restrictions) for both radiological and personnal safety.
It is OK to repair something with a like for like but under no cicumstances can the physical facility be changed without a typically cumbersome and time consuming design package. Even temporary jumpers for troubleshooting require a level of independent review. Absolute verbatim compliance with all procedures is mandatory and anything less is not tolerated. No work can be done, even a simple repair, without an approved work package. Individual accountability is held to very high standards. Independent verification and real time independent work observations are an everyday occurence. Then there are the many restrictions and administrative requirements associated with entering areas that that are potentially contaminated or are in radiation fields. All this, plus much more, make for a very frustrating experience for new people, especially those with "fossil plant" experience. Things just don't happen quickly and there are always many barriers to get past to do even the simplest tasks.
Now the other side. I enjoy working in this enviroment. The work is challanging and exacting. The abilities of the people working in this industry is clearly very high. It is very satisfying to consistently work with people that are highly competent, reliable, and accountable.
Having said all this, my only advice to someone entering this industry would be to tell them they absolutely must be willing to except a huge culture change from the expectations of most other industries. Those who fight or even just complain about all the "silly" requirements make themselves and everyone around them miserable.