Russmech, I don't think I fully undersand what you are trying to do, but the requirements for the makeup air are typically to supply the exhaust volume or slightly more. If you know the building exhaust and supply volumes and the exhaust exceeds the supply, you can reasonably assume that the infiltration volume is the difference between the two.
Building pressure will vary with tightness by:
Q = 2610 * A * dP^.5
where Q is the flow in cfm
A is the net open crack area in ft2
dP is the differential pressure, in inches of water
Regardless, if the flow is known and stablized by use of VAVs/CAVs with flow stations, the difference in cfm should be the infiltration.
If you don't know these volumes because you don't have a recent TAB report or design drawings, a tracer gas test is the best option - apply sulfur hexafluoride (or other tracer) to the building to achieve a known concentration and monitor the decay concentration at certain intervals to determine building air exchange. This air exchange should coincide with known mechanical outside air. The offset between the ventilation results of the tracer test and the mechanical air intake volume will be the infiltration.
Those are some general notes about the subject, but I'm still unsure about your specific question. If you've recently installed a combustion appliance and are trying to circumnavigate code for make-up air, I recommend (for your own protection) to ventilate as prescribed, especially if you have no idea how tight the building is. These inspector-types are "sticklers" because people have died from messing up combustion make-up air.
Anyway, I hope some of these thoughts help. -Chas