nunorodrigues... hope this makes sense... A few thoughts.
1. Sealants for Integral Fuel Tank application.
1.1 Sealants qualified to AMS-S-8802* are considered the gold-standard for integral fuel tank sealant. These sealants generally have little/no corrosion inhibitive pigments, hence retain high fuel resistance/adhesion/toughness for decades… at the cost of poor performance in a corrosion-prone [exterior] environment.
NOTE. 8802 sealants are generally over-coated with corrosion inhibited 81733 sealants in fuel-dry environments for increased corrosion resistance.
Types
Sealing compounds covered by this specification are classified as follows:
Type 1 - Dichromate Cured Sealant. Material with a dichromate curing agent.
Type 2 - Manganese Dioxide Cured Sealant. Material with a manganese dioxide curing agent.
Classes
The following classes apply to both Type 1 and Type 2 sealing compounds:
Class A - Suitable for application by brush. Available in the following application times in hours:
A-1/2
A-1
A-2
Class B - Suitable for application by extrusion gun or spatula. Available in the following application times in hours:
B-1/2
B-1
B-2
B-4
Class C - Suitable for extrusion gun, spatula, brush, or roller. Available in the following application times in hours:
Notation: ( ) Assembly time in hours:
C-8(20)
C-8(48)
C-24(80)
1.2 Sealants qualified to MIL-PRF-81733 [any class] are generally considered pressure/environmental sealants with corrosion resistive pigments [fillers]. This spec relates to a family of sealants that at best, is for secondary fuel sealing ONLY, IE: fuel-cell cavities where there is minimal exposure to fuel [except in fuel bladded leak]. The corrosion resistive pigments reduce adhesive strength; and because they ‘leach’ the corrosion protective pigments when exposed to fluids [water, fuel, oil, etc], tend to decay slowly over-time. In an environmental/pressure environment, this can be acceptable… however, this is NOT acceptable for a long-term 100% reliable integral fuel-tank seal.
Now here is where I am concerned.
You stated the sealant You are using is MIL-PRF-81733 C12. Based on specification MIL-PRF-81733, this is meaningless. This sealant is specified in the following order [see MIL-PRF-81733, para 6.2]…
MIL-PRF-81733-{Type}-{Class}-{Grade}-{-Application Time ‘dash number’}, thus…
Types. The types of sealing compound are as follows:
Type I - For brush or dip application
Type II - For extrusion application, gun or spatula
Type III - For spray gun application
Type IV - For faying surface application, gun or spatula
Classes. The classes of sealing compound are as follows:
Class 1 - Polysulfide rubber base material
Class 2 - Polythioether rubber base material
Grades. The grades of sealing compound are as follows:
Grade A - Contains chromate corrosion inhibitors
Grade B - Contains nonchromate corrosion inhibitors
Application time. The minimum application time**, in hours, for each type and class is indicated by a dash number as follows:
Type I, Class 1 - Dash numbers are -1/2 and -2
Type I, Class 2 - Dash numbers are -1/4, -1/2, and -2
Type II, Class 1 - Dash numbers are -1/6, -1/4, -1/2, -2, and -4
Type II, Class 2 - Dash numbers are -1/4, -1/2, -2, and -4
Type III, Class 1 - Dash number is -1
Type III, Class 2 - Dash number is -1
Type IV, Class 1 - Dash numbers are -12, -24, -40, and -48
Type IV, Class 2 - Dash numbers are -4, -12, -24, -40, and -48
>>>>> There is NO designation ‘C-12’ for this sealant.
1.3 NOTES.
1.3.1 Roughly speaking, ‘application time’ is the time span when fully mixed sealant has to be applied to the structure. It will have high-adhesion and good fluidity up-to this point.
1.3.2 Roughly speaking, ‘assembly time’ is the time span when fully mixed sealant that has been applied to structure, can no longer be readily squeezed-out from joints, the sealant [such as fillets] successfully manipulated and/or mating parts be successfully repositioned… without sealant damage… because it has begun the final transition from a tacky polymer liquid to a semi-solid polymer. Assembly time is roughly 1.5-to-2.5 X the application time... unless specifically formulated for an extended assembly period.
1.3.3 Examples.
Type I-1/2 designates a MIL-PRF-81733 brushable material having an application time of 1/2 hour with an assembly time roughly 0.75-to-1.25-Hours.
Type I-2 designates a MIL-PRF-81733 brushable material having an application time of 2 hours with an assembly time roughly 3-to-5-hours.
Application and assembly times are influenced by a number of factors: however, after individual chemistry variations of each batch of sealant, humidity and temperature are the greatest contributors.
1.3.4 CAUTION. I always recommend that the first a bead of each mixed sealant batch be applied to piece of primed sheet metal. Flatten the bead using a squeegee to ~0.020—0.040 thick [notch-out the squeegee blade to attain this flat profile. The sealant tech should note the mixing start time adjacent to each sealant bead [sharpie pen]; then check the consistency of that sealant frequently, to ensure it is still within the assembly time… experienced mechanics will ‘know’ when this point is crossed.
1.3.5 NOTE. I thought that ‘C-12’ might have come from the manufacturer’s ID on the label… however I had no luck confirming this possibility.
2. You seem to need more than a briefing on this topic. Here are useful references [plus where to find on web]…
NOTE.
I tried to find a web-link for the
AFWAL-TR-87-3078 Aircraft Integral Fuel Tank Design Handbook which is an extremely detailed design document. HOWEVER... even though it is almost 30-YO... I think, it was recently reclassified [with a lot of other/similar documents] based on original cover-page markings to ensure DoD controlled/restricted access. Perhaps a corporate, university or national library has a copy You can review/use. IF there is a US defense aspect to this work, then DTIC
might release a copy to Your company.
MIL, MS, etc specs…
Search Document ID MIL-PRF-81833 and MIL-S-8802 [predecessor to AMS-S-8802], etc…
SAE documents…
AIR4069 Sealing of Integral Fuel Tanks [must have]
AIR786 Elastomer Compatibility Considerations Relative to Elastomeric Sealant Selection [good-to-have]
AIR3270 Aircraft Sealant Removal Techniques [good-to-have]
AGARD-R-771 Fuel Tank Technology [must have, poor quality scan]
PPG Aerospace Sealants
Various PPG products qualified to meet sealant (and related) specification requirements [see individual data sheets]
USAF Integral tank sealing, and related, T.O.s (general technical manuals for practical applications)
1-1-3 INSPECTION AND REPAIR OF AIRCRAFT INTEGRAL TANKS AND FUEL CELLS [must have]
1-1-8 APPLICATION AND REMOVAL OF ORGANIC COATINGS, AEROSPACE AND NON-AEROSPACE EQUIPMENT [good-to-have]
1-1-691 CLEANING AND CORROSION PREVENTION AND CONTROL, AEROSPACE AND NON-AEROSPACE EQUIPMENT [good-to-have]
Regards, Wil Taylor
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