I'd love to be able to show you how to do it, but my company has restricted access to any web hosting services. So here are some instructions:
1. Create a new part
2. Go to Tools->Equations and hit "New..."
3. Enter "Side = 1" (without quotes)
4. Hit "OK"
5. Hit "New..."
6. Type in (or copy/paste) the following line:
"Rad"= "Side"/2 *sqr(1+((1+sqr(5))/2)^2)
7. Hit "OK" and then "OK" again to exit the Equations dialog box
8. Create a new sketch on the top plane.
9. Draw an equilateral triangle centered on the origin. To do this, draw the triangle around the origin, then draw construction lines from each vertex to the origin. Make all three construction lines equal length, and make all three sketch lines for the triangle equal length.
10. Add a dimension to one side of the triangle. Right-click the dimension and choose "Link Value." Choose "Side" from the dropdown box.
11. Exit the sketch.
12. Create a new 3D sketch.
13. Draw a construction line normal to the top plane starting at the origin.
14. Draw a construction line from one triangle vertex to the end of the other construction line.
15. Add a dimension to the length of the second construction line and link that value to "Rad"
16. Exit the 3D sketch.
17. Select the two construction lines of the 3D sketch and to to Insert->Reference Geometry->Point. This will create a reference point at the intersection of the two construction lines of the 3D sketch.
18. Go to Insert->Boss/Base->Loft. For the Profiles, choose the 2D sketch and the Reference Geometry Point created in step 17. This will create an almost equilateral pyramidal tetrahedron. The base of the pyramid will have edges of length 1 and the other faces will have two edges of length 0.951057....
19. Choose one face of the pyramid and one of its 0.951... length edges. Create a circular pattern, 360 degrees, equal spacing, five instances. This will create a sort of flying saucer shaped body. Choose another 0.951... length edge and any face of the body and create another 360 degree, equal spaced, five instance pattern. The pattern will overlap itself in several places. This is OK. It will create an almost complete icosahedron.
20. Choose one more 0.951... edge and create one more 360 degree, five instance pattern. Your icosahedron is complete.
To change its size, change the equation "Side = 1" to whatever side length you want.