Psmart is correct that you could compute a theoretical CN based on soil storage, it's a starting point, BUT:
* How do you account for antecedent moisture?
* Consider that SCS/NRCS engineers have said "It is sometimes inferred that the parameter S... is a physical property of the site like a soil moisture storage parameter...This has not been shown with any certainty. The parameter S (or CN) is a model variable and is only a constant for a particular storm." (reference: Runoff Curve Number Method: Beyond the Handbook
* How do you know that the 0.2S abstraction inherent in CN methods is relevant to green roofs (it's not!)
* How would you compute the time of concentration for a green roof? (- did you know that the time of concentration for a conventional CN analysis is not really about time, but it is derived from the slope of the storage:discharge curve for a particular basin, per the original SCS documents [Reference: SCS Hydrology Tech Note 2 Chapter 1 "The Modified Att-Kin Routing Model"]. I've performed detailed seepage analysis then back-calculated the corresponding Tc and shown it is can be much longer than on a conventional roof when an aggregate drainage layer is used for the green roof.)
* How do you account for flow time (and storage) in a lateral drainage layer?
I only bring these issues up because it is not clear or obvious how to adjust a CN method for green roofs, particularly if you are trying to estimate both runoff peaks and volumes accurately. If you must perform a CN analysis for the green roof consider that you might use different CNs for volume and rate analyses, and you must somehow account for the anticipated antecendent moisture.
My opinion is that the standard methods of analysis/models are ill-suited to account for BOTH volume and rate estimation for green roofs, and to analyze those aspects separately is not conducive to detention design based on level pool routing for a typical site, where "conventional" areas of the site would be analyzed using CN methods yet green roof hydrologic response could influence the detention sizing.
As a quick check, you might consider the extent of green roof coverage is on the site. If it is less than say 20%, it may not warrant extensive modeling as the rest of the site will likely drive any detention sizing.
BLT