Why not use something like SOLID186? I have no experience in this type of analysis, so take my advice with a grain of salt. But I believe for this element you can define up to 250+ layers, material properties which vary from layer to layer, orientations, etc. Material properties can be defined using the TB or MPXXXX commands. Layer properties should be defined using the SECXXXX commands. Give the Ansys documentation a look through regarding your question.
-Brian