You can try vapor charging a little more at a time while watching the evaporator air temperature. From a slightly undercharged state, the temperature should fall, then start to rise. I stop adding refrigerant when it's risen about 1...2 degF. I don't know if that's really an optimum, but it works okay in the backyard.
OR you can try measuring temperatures and pressures and calculating the superheat and subcool temperatures, as the refrigerant manufacturers recommend. I've tried it on occasion, but never trusted the numbers because I couldn't get temperature readings that I thought represented the temperature of the refrigerant, by measuring the exterior of various tubes or fittings, and I wasn't prepared to open the system to install temperature probes.
Mike Halloran
Pembroke Pines, FL, USA