For your purposes, the "S" numbers apply. The charpy impact requirement forces you into considering supplementary essential variables, but that isn't insurmountable.
15 ft-lbf at -20 deg C works out to 15 ft-lbf at -4 deg F. For FCAW, E7XT-1 is rated for 20 ft-lbf at 0F. If you control your heat input properly, you'll probably get there using this filler metal, but a 75% (or 80%) argon + 25% (or 20%) carbon dioxide shielding would help. Straight carbon dioxide shielding gas probably won't make it on a consistent basis.
E7XT-5 will also work with an argon-co2 mix, but is intended for flat and horizontal welding.
E7XT-6 (for flat and horizontal) and E7XT-8 (for all positions) are self-shielded FCAW wires (spatter-matic specials) that are also rated at 20 ft-lbf at -20 deg F, and should do the job.
For all intents, you should only need to pick one filler metal wire for the FCAW process -- and that comes down to whether or not you want gas shielding or self-shielding. I always favor gas shielding, especially for shop environments -- but I'll admit that I'm not a fan of spatter-matic on any given day.
After that, ASME SC IX makes things pretty straightforward.
You'll need to qualify the A588 to itself at two thicknesses -- I would use 1/4" and 1/2" to satisfy the requirements of QW-403.6. That gets you a qualified range of 1/8" up to 1". QW-424 effectively says that a P3 (or in this case S3) welded to itself also qualifies for a P3 (or S3) to a P1 (or S1), if all other essential variables are the same.
You'll also need to run a pair of A572 Gr 50 test plates, again using 1/4" and 1/2" thicknesses.
The 1/16" wire should do the trick, unless you have more plate in the 1/4" and thinner range being used, in which case an 0.052" (or even 0.045"

diameter wire may be useful. In any case, qualify the test plates using the 1/16", because if you can make your Charpy values with that heat input (which you will have to control), you will be able to use smaller diameter wires whose heat input is equal to or less than that of the 1/16" wire.
4 PQR's are what you need. Lotsa luck.
Matt Nousak, P.E.
Senior Staff Engineer
Metallurgist/Welding Engineer
Middough Associates Inc.
middough.com