I agree paragraph two is a bit vague.
I simply have a flame, and cut a sliver of the plastic and grasp it with tweezers and slowly approach the flame with it. If it melts before decomposing, it is thermoplastic, if it decomposes without melting it is thermoset.
Thermosets may leave a sticky residue as a product of decomposition, but that does not mean they are thermoplastic.
If you are not well experienced with the sniff test, samples of known material to use as a reference are quite valuable.
The sniff test was much more conclusive before flame retardants, rubber modifiers and alloys were so common, as the afore mentioned factors can create a confusing smell.
Another very basic test is the floatation test. If a solid piece of the plastic, with no bubbles or voids, floats, it is a polyolefin. If it slowly sinks it is a plastic with an SG of over 1.0 but less than 1.2. If it sinks like a rock, it probably has an SG of over 1.2.
Still another is to compare surface hardness and surface feel.
Some tests with basic equipment are to determine an accurate SG, measure surface hardness, measure melting temperature.
A rough house melt temperature test is to place a small piece of the plastic between different known samples on a cold hotplate then turn on the hotplate and note the sequence of melting.
Regards
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