Dear All,
We concluded the failure analysis of metal loss in the hot water generation system.
Root Cause - Chemical Compatibility and Behavior at High Temperatures:
It is evident that the chemical (NORUST SC 47Z UAE) is unsuitable for closed systems or applications at temperatures exceeding 80°C. At higher temperatures, ammonium bisulfites decompose, emitting various gases and solid residues.
While the specific decomposition byproducts depend on reaction conditions, they typically include ammonia (NH3); sulfur dioxide (SO2); water (H2O), and some other possible substances.
The decomposition reaction above 80°C can be represented as: 2NH4HSO3 (aq.) -> NH3 (g) + SO2 (g) + H2O (g) + NH4HSO4 (aq.). This indicates the release of gases, including ammonia (NH3) and sulfur dioxide (SO2). These additional gases contribute to the water's overall gas content, thereby impacting the NPSHa calculations.
The impact of this decomposition can vary depending on the context. A few possible impacts to consider are oder, toxicity, and corrosion.
Root Cause- Operating Conditions Review:
The combination of high temperatures, chemical decomposition, and operational conditions below the pump’s ideal curve creates a scenario where cavitation is likely. The high temperature contributes to the chemical decomposition of the oxygen scavenger, leading to gas formation which exacerbates the formation of vapor bubbles. When these bubbles collapse, they cause the physical damage observed.
- Sensitivity calculations show pumps could be experiencing cavitation during high water temp return at suction (>105°C) – high DP of 0.6bar observed over inlet strainer of Pump A and 0.4bar Pump B could be contributing to cavitation
- Inconsistencies of flow meters and Pump DP – recommend recheck of flowmeter calibration / dp checks and flushing – or there maybe clearance issue between impeller and casing impacting performance – ongoing,
- Pumps possibly operating beyond their rated case of 200m3/hr. (down the curve) observed from low pump differential - estimated flow 260m3/hr. and (9m NPSHR).