"A" is close enought to what I calculated (you don't say what the missing 4% is, but 490 BTU/SCF should ignite just fine).
From the BTU content, the missing 54% on "B" must also be inert. "B" would probably burn, but I would think that the ignition temp would be really hot (100% methane has an autoignition temp around 1,000F) and wouldn't be suprised to see that it had to be exposed to 1,500F for a prolonged period to ignite. I'd be reluctant to try to run 167 BTU gas into an engine.
David